Page 8 - Clothesline - November 2020
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PAGE 8 / NATIONAL CLOTHESLINE / NOVEMBER, 2020
              THE SPOTTING  BOARD                                                                                   BY DAN EISEN











          Breaking down chemical reactions




            f you understand  true  oric (rust remover)?            Acid Used for Spotting        spotting agent.              The dyes on silks and wools
            chemical action the proce-   Answer: Acetic acid.          Tannin formulas are pre-                                must be carefully tested.
          Idures you undertake for       Let’s start. In order to be a  pared formulas consisting of   Oxalic Acid is a useful  Spotting Tannin Stains
          stain removal will be easier      chemical it must be soluble in      a mild acid mixed with a  acid in removing many types   Tannin stains are veg-

          and more proficient. Chemi-  water and acid or an alkali.   wetside lubricant. Tannin      of tannin stains, especially  etable or are obtained from
          cal action is the changing of  This means that drycleaning  formulas are usually safe to  berry, cherry and wine. It is      plant sources. Examples of
          the properties of the stain to  solvents, amyl acetate and  fabrics and are not as strong  also effective on rust and  tannin stains are coffee, tea,
          make it either invisible or  volatile dry solvents which  as most acids used in its pure  metallic stains. It is also a  liquor, wine and soft drinks.
          water soluble. Before we start  are not soluble in water and  chemical state.           mild reducing agent which  Tannin stains respond best to
          understanding chemical ac-   therefore cannot be termed      Acetic Acid has a strong  makes it effective on dye  acids. Never use alkalis or
          tion, why don’t we take a lit-  chemicals.  You may argue  relationship to vinegar. Vine-  stains. It is considered a more  protein formula on tannin
          tle  quiz   to   test   our  this but we need this defini-  gar is produced through the  aggressive chemical and  stains because the stain will

          knowledge of chemicals.      tion to explain how chemi-   action of bacteria on yeast fer-  should be tested for the  become set and often impos-
            If I put sugar in water, is  cals work in spotting.     mented brews. Vinegar can  safety of dyes on fabrics. You  sible to remove.
          that a chemical action?                                   be made of any plant that can  can order oxalic acid from    Flush.
              Answer: No. You are only   Acid Facts                 be fermented to form alcohol,  your jobber in crystal form   Neutral Lubricant.
          changing the physical state    Acids are defined as chem-  which is subsequently con-   and mix with 20 parts water.      Mechanical Action.
          of the sugar, but chemically it  icals that release hydrogen  verted to acetic acid. Acetic  Laidlaw Chemical Co. sells      Flush.

          still remains the same sugar.      ions in the presence of water.  acid is more effective than  oxalic acid as a rust remover.      Tannin Formula.
          This is an example of wetside  The  pH, or potential of hy-  tannin formulas on some tan-  The product is called Rustaid      Mechanical Action.
          solvent action.              drogen,    measures     the  nin stains such as wine and  and is already mixed so it      Flush.
            Is the strongest acid bat-  strengths of the acids.  Any  liquor. Some people do not  makes it easier to use.          Acetic Acid + Neutral Lu-

          tery acid or the acid found in  number under seven means  like using acetic acid because   General Formula is a mix-  bricant.
          the human digestive system?  that the substance is acid in  of its odor. Add a little neu-
                                                                                                  ture of a lubricant, alcohol,      Mechanical Action.
            Answer: The digestive sys-  nature.                     tral lubricant to the acetic      and a mild acid. It is very ef-  Flush.
                                                                                                                               Oxalic Acid
          tem contains a stronger acid,   Acids are used for tannin  acid and the odor problem is  fective on ink stains and dye
          which is hydrochloric acid  stains, inks, dyes and medi-
                                                                    solved. When using acetic  but not generally very effec-       Test Fabric.
          while battery acid, which is      cines. Acids neutralize alkali.  acid remember to order it at  tive on other tannin stains. Be   Heat.
          sulfuric, is slightly weaker.   Alkali are capable of causing  28%. It is also advisable to di-  careful using it because the      Flush.
            Which is stronger – acids  color change on fabrics.  lute this down with a little  alcohol content may be dan-         General Formula.
          used in tannin formulas for  Acids neutralize the alkali  water to bring the concentra-  gerous to the dye on some      Test Fabric.
          r     emoval of citrus stains or  which in most cases can re-  tion to about 20%. Acetic acid  fabrics.  General  formula      Mechanical Action.
          acids found in citrus stains?   store the color.          may be safe and used as a  should not be used if the      Flush.
            Answer: About the same.      Heat accelerates all chemi-  general spotting agent but  stain is protein or albu-        Rust Remover.
            Which is more likely to  cals which means a relatively  when it is heated it may affect  minous in nature. The alcohol      Test Fabric.

          cause color loss on a rayon      safe acid can become much  acetate fabrics. Besides using  will set these type of stains.       Heat.
          and acetate fabric, either  stronger
                                                  and   dangerous  tannin formulas learn to add                                    Flush.
          acetic acid (33%) or hydroflu-  when heated.              acetic acid as an additional  Acid Used for Spotting           Protein Formula to Neutral-
                                                                                                    Rust Remover is hydroflu-
                                                                                                                               ize Rust Remover.
                                                                                                  oric acid. This is effective not      Flush.

                                                                                                  only on rust stains but on     Peroxide (3%) Plus Ammo-
                                                                                                  many types of tannin stains.      nia.
                                                                                                  Rinsing is difficult and I have      Test Fabric.
                                                                                                  found that the best way to     Heat.
                                                                                                  flush and neutralize rust re-      Flush.
                                                                                                  mover is to use a neutral lu-      Acid.
                                                                                                  bricant or a protein formula.      Flush.
                                                                                                  This will not only aid in re-      Feather.
                                                                                                  moving it from the fabric but      At any stage that the stain
                                                                                                  it will neutralize any trace of      is removed you would then
                                                                                                  the rust remover. Keep rust      stop the procedure.
                                                                                                  remover away from metallic  Protein Procedure:
                                                                                                  fabrics, metallic ornaments    Flush.
                                                                                                  and glass. It is also advisable   Neutral Lubricant.
                                                                                                  to test the safety of this acid      Mechanical Action.
                                                                                                  before using on the fabric.        Flush.
                                                                                                                                   Protein Formula.
                                                                                                  Alkali Facts                     Mechanical Action
                                                                                                    Alkalis release hydroxyl in      Flush.
                                                                                                  the presence of water. Alkalis      Ammonia Plus Neutral Lu-
                                                                                                      e effective on protein and      bricant.
                                                                                                  ar
                                                                                                  albuminous stains. It is also      Mechanical Action.
                                                                                                  effective as an aid in remov-  Flush.
                                                                                                  ing ground-in soil. It will      Digest – If stain is stiff.
                                                                                                  neutralize  color   change      Flush.
                                                                                                  caused by an acid. The pH of      Peroxide (3%) + Ammonia
                                                                                                  alkalis are measured in num-      Test Fabric.
                                                                                                  bers higher than seven.          Heat.
                                                                                                                                   Flush.
                                                                                                  Alkalis Used for Spotting        Acid.
                                                                                                    Ready-made protein for-        Flush.
                                                                                                  mulas are mixed with a mild      Feather.
                                                                                                                               Dan Eisen, former chief garment
                                                                                                  alkali and a lubricant. It is
                                                                                                  relatively safe and effective,
                                                                                                                               analyst for the National Cleaners
                                                                                                  but should be tested on      Association, can be reached at
                                                                                                  wools and silks.             (772) 340-0909 or (772) 579-
                                                                                                    Ammonia (26) is used for   5044,    by     e-mail   at
                                                                                                  spotting protein and albu-   [email protected]     or
                                                                                                  minous stains. It is stronger   through his website at www.gar-

                                                                                                  and more aggressive than     mentanalysis.com.
                                       To learn more, visit www.natclo.com/ads                    ready-made protein formulas.
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